If inhaled : Consult a physician after significant exposure. Stability and Reactivity Stability: Stable at room temperature in sealed containers. ±K~AVxó[email protected]'ZMِ¥ó#ü Symptoms include itching, burning, redness and tearing. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpžJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��᪟"! Cyclohexene is a hydrocarbon with the formula C 6 H 10. Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. CHEBI:88428. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. This cycloalkene is a colorless liquid with a sharp smell. 5 0 obj MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. Linear Formula C 6 H 9 OSi(CH 3) 3. stream Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. S^õ¾»è°s²ß{_)Œ/)Ï|5¸£ƒ vRŒŸáHGÇmŠPûÁg…9ýÂŽ—ù@,;ëš½D÷Nl=ƒÃ ÝQŒÏ˜¹Å™šO #K¶Ä¬;ûËÇõF.¯8Ífåü .9ù-¿ñι~ZoÇæÝ á¬ñ‡˜ÔÊè­¾F.ñh>©j&©žOӕϠ“”¤mç}íýQ[x¾0"åÛÀOæäZcyÔ M ®æà.ßUñѪRЄÔ=’ÿŽY³Ç&0æüYUùŸ+«ˆ9.áhF€Úž¨ŠMÛ¨ ýÀ*M¾>_û¢dµ&$jl #½>6¡UFü®u§ÞùْlÑ1HJ½$˜Ëz×ì1Ì=–£ãbFÀ”‘÷‡øuOÅäž ƒE¶h’Zúظ“õ.ۏ×óæ†Ä¹×œ;f ´¬"+‡ºO}˜®)[-,v‰ä݄üò¼i¢^RZ è3‹›w‘uޖ½¡9Tf®Õ½@çÿ%|C–á,´iαBÓ²“8*ȱoå8¸±ãsx"ëÀŠ&eÑgrL&µâˆ6(±eÝÔ»Ô@«íë£Mâ@HÛ~ö¹ˆ¹Ä—ßٝlVÄTN—‰VÙ¦ "÷SF÷Š"HɘµÏÿ¾Z²nBýM×záÉNŠ\ÎÉâãv5â‰áÁåÄäü-ç°ôº>HÖz :•Mð-$yèAœÇYXY²j;-Ë'¹ ;Y ½w½ù՜]Ó±C-]ÿÍ=] NACRES NA.22 a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ BRN 1560601. ghl.PD_Mitscher_leg0.699. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. EPA Pesticide Chemical Code 219700. May react exothermically with reducing agents to release hydrogen gas. Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 6 0 obj <> H315 Causes skin irritation. -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem – fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. AI3-19937. Cyclohexene Flinn Scientific, Inc. P.O. Incompatibl Articles of 2-Methylcyclohexanol are included as well. 3 Effective date : 12.20.2014 Page 2 of 7 Cyclohexene Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Read label before use Keep container tightly closed Avoid release to the environment Do not eat, drink or smoke when using this product 3-methylcyclohex-2-enone. endobj MATERIAL SAFETY DATA SHEET Cyclohexane MSDS Number: BDH-160 Page 2 of 9 POTENTIAL HEALTH HAZARDS SKIN: Irritating to skin. Search results for 1-methyl cyclohexene at Sigma-Aldrich. *Please select more than one item to compare nutty cyclohexenone. Read label before use. Material Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 09/13/2011 1. . Now wash the cyclohexene (where is it?) Keep out of reach of children. with 10% sodium carbonate solution (10 mL). Address: P.O. Material Safety Data Sheet Cyclohexene, 99% ACC# 00500 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexene, 99% Catalog Numbers: AC154840000, AC154840010, AC154840025, AC154842500, AC154845000 Synonyms: Benzenetetrahydride 1,2,3,4-Tetrahydrobenzene @��|���ܴN��Y����z�t� D XX�[�OԲ\V��^�o��YO��n?T=!6NY�\s�0M2����� Z.t�Iw}B���; �E��:�����P'��5�� F`��&���B\Q�O��>��ץ�7�p�!B^6�qD�H�Z3h���|��c�l�zC�yŋk�BEm̦��a�\9IuL&t)��~�x�B&��:˂O�T �1���m��d�G�FJN�ї[��ݮ'o��=#���jL�BXN)U[X�MV�J� 1��PU|k�+�!$��v�#���5���/&�H[5�(�)�h�͸�(��L8��+*�9 |���9ޣ �=����J8ͫE]��\M�I�a�oc=$#g�Z��m��]�� Y�x�4Q�����64�R�Z�s�4�%͟�2c*xs�>- �7����4H�$6�|��|�Bq#:����.�vt��DM��K��ˊ�1�O���sN�4��� k m Wh̐=W����{���b�&�,��hLng[�l���(»��R�]��L���LD��9b?|Z�2�vtz����z�ˊҩ!��5)[email protected]�ϵ��� � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr ��&��l�@L'/������\����$�/�GjEz ��1��P�2�׸��.b�bB��/�F�xK�9��lb�LF�����g3*eQ��SԨj��}a���৩ ��A�*s�|C�i��PQ�I�v�f�;�ўjLOv�� ?�o"��F\ɇ��ҌD�T]�Ҭ3�p�L�t�o���H�&9����5�^�~�P���(R]+��Z�0���x�t�:]����l�T���;�"G��d`�!�m���吏/~�d���%|�@U���=݋$&*(SX�r�����j��Y�e����5ZM����"��ҊL뼞S�!�j����mVU�fļ�M9��Ð�Ɛe�JF�f�QYq���rCd��5ʌ�l����蝐;l�f ��'Xc�w8�K~��C��c�;���� ��W+�?g�]�)By���r���T���aP$�N���XĄbL�s��! Do not leave the victim unattended. /Contents 6 0 R>> The two layers are shaken together briefly, whereupon spontaneous heating occurs. %���� CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. tHk©âî°û:#;ì.^M1jŽk¾˜Bôœ[email protected]ß@ׯ£óq9Í©bc¯½h›þGÌÀíV®í¤šv“¼þ{¿ßS3öªÀÆQuØáCU±Qc!æý‡ç[›jàŸÿ³à'&_Ll’ÐzÐ눘¨ê±JאYm˜“ã ENEC0620 - CYCLOHEXENE CYCLOHEXENE Safety Data Sheet ENEC0620 Date of issue: 08/29/2016 Version: 1.0 08/29/2016 EN (English US) SDS ID: ENEC0620 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. PubChem Substance ID 24848686. Cyclohexene (density 0.81 g cm-3) will separate out from the water. m���D��v�����D�=�� ��f%h��������ʜMk_�n`� +��$7��R�����*c&��Χ����.�7:����Vv~�H�І���D`��z�]WM�����A[o�'�C�$��R�\��8�z��l���\�+��-9�"�uZ�Ai��b��\ A���:�_twu�M�bV Yu3j���B���Uă�!�gW~�^/Z����[@ �ْ�ն�����\׃�m2D#]��3���?��O���hWlALsނ-���¿��w�8�Nj�!K�^Jթ�&��B* ���erQ4XK�Fѧ�>%ӗ�tE�]��Ga��)��ċ�R����[R�y��>�C4˔K\K�����+�`5U�j���w�ǚ.�(��g^�7�ׂ��V�2��� k|Ys�����{�l'�V�>&5�ܠ����p���Ş���)#�k~rNy��X2��hE�XZ���6��/C����/�����Z���1����@��2��=y�x�O]^'�C���L��TQ��bGѮV��{\G��Y�$�+�[email protected]�ޟ�#��Ȩ�I�����P�Bz�."?�8��\�szIb>D�ol��ho��ݥ������t3;&���G(r$S8�"���Φ`=��ϧ�����ރ�L]��y�,��Zc�[email protected]`�)bp,����? 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email [email protected] Emergency telephone 08:30 … Search results for cyclohexene oxide at Sigma-Aldrich. 3-methyl-cyclohex-2-en-1-one. 3-Methyl-2-cyclohexen-1-one, 98%. If unconscious place in recovery position and seek medical advice. Chemsrc provides 2-Methylcyclohexanol(CAS#:583-59-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. The mixture becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam bath. EINECS 214-769-7. Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98–100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 4 0 obj endobj Beilstein/REAXYS Number 1859394 . Material Safety Data Sheet Page 1 of 2 ... Cyclohexene MSDS # 243.00 Section 1: Product and Company Identification Cyclohexene Synonyms/General Names: 1,2,3,4-tetrahydrobenzene Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: [email protected] It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. Material Safety Data Sheet Cyclohexanol ACC# 00499 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexanol Catalog Numbers: AC147680000, AC147680010, AC147680025, AC147680050, AC147680200, AC147685000, S79991, C558-500 CYCLOHEXENE may react vigorously with strong oxidizing agents. <> 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. )����[Y�:������c��& ���Ҁ�{�' �v��~m�SC��[email protected]���HCޑ1I�� �_� �KZnMC�3����|A|����;�D��d���;;���+N EYES: Irritating to eyes. Run off the aqueous layer. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. endobj Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. The structural formula for Cyclohexene is: WHAT IS CYCLOHEXENE? Molecular Weight 170.32 . Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Cyclohexene is one of the chemical products on offer here at Chemoxy.. 's�'���>7TD�I)^��j�ќ�8ȼ�?b$�ȸ��,xv~'z��N��9�ZZ��%�-�7'��9�Ȱ��*���p(�M��WT����>���3��������S�/?5y�� v��O[m�d�d�>c:��2���Y�st[K2�y$�WL��;P�օ����m�[�� LJ��U?Q*0φ����F�o�-j�� ]�w�W�'R��$9 q�K��7~��;�0 {���zpz������`�ͼO�q���t��)ytM���4ɶ �L�!��x�;-q���[���� W�Cϑ�*��:��D��ղ�;�VN�+�T��P���fzs�.���Z�_�pG�������DU���#�D�N�����&IZ�i_��Cl� ��]`�V����a���%�AWd�d`�g]���P]\?��H5�2� 9��R� 3 0 obj H304 May be fatal if swallowed and enters airways. Brookfield, Wisconsin 53045 262-792-1450 262-792-8721 Fax 3-Methyl-2-cyclohexene-1-one. endstream Conditions to Avoid Excess heat. MFCD00001581. <> UNII-786Y352V9X. %PDF-1.4 In case of skin contact : If on skin, rinse well with water. Keep out of reach of children. ?��������� �\h(��.^���Lma�bjon�S�N*ejN��+��b!�ݖ���h�A���% �o�4}�,�$�Q�E�n�J �R�� EC Number 229-675-1. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) It is an intermediate in various industrial processes. MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. /Contents 4 0 R>> 4-Vinyl-1-cyclohexene, stabilized Revision Date 18-Jan-2018 Decomposition Temperature No information available Viscosity 0.7 mPa s at 20 °C Molecular Formula C8 H12 Molecular Weight 108.18 10. 786Y352V9X. Safety Data Sheet (SDS) SDS #: 292. �/?Gx�;�O�Ip{��9���Jm�*�f/����41�uX���Վr��C�V�eF����@�],2�c�3� ��t����5��j�[email protected]������l6d���NA���fk49G4���v�. Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� This (M)SDS is a generic document with no country specific information included. Compare Products: Select up to 4 products. It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. T��ud�m_ �,�"+���F��l4����Y~ <> Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. 3-Methylcyclohexenone. /�d��[email protected]��YQ+_v��j�`��ug����..'[#�|Z`. Compare Products: Select up to 4 products. MDL number MFCD00001541. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. ����" �x�K'R��N#˒�k�E5R4��q���/W�D�S9��4�p+������-u5p�e*a��.��R�+��?� o.�H��Z��ɝ��Cط�#t��g�ӛ�=!dq����Y���͆h��88_��i� &C��b�9���f��ql�N�{f��Mj# Cyclohexene is used as a solvent. Allow the layers to separat and run off the aqueous layer. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger NSC 43632. stream Hydrite Chemical Co. 300 N. Patrick Blvd. PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Cyclohexene has been used in the green synthesis of cyclohexene oxide via hydrogen peroxide epoxidation in glycerol-based solvents using bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide as a precatalyst. ���U�� Ùx£4¹¹æZ¢zˆŽ×|‹Ÿ0‚9µ ÎÉ°•ÖÚµ,4tß=¯˜&. *Please select more than one item to compare Revision Date: March 25, 2014.